Anisotropy of the magnetic properties and the electronic structure of transition-metal diborides

被引：11

作者：

Fedorchenko, A. V. ^{[1
]}

Grechnev, G. E. ^{[1
]}

Panfilov, A. S. ^{[1
]}

Logosha, A. V. ^{[1
]}

Svechkarev, I. V. ^{[1
]}

Filippov, V. B. ^{[2
]}

Lyashchenko, A. B. ^{[2
]}

Evdokimova, A. V. ^{[2
]}

机构：

[1] Natl Acad Sci Ukraine, BI Verkin Inst Low Temp Phys & Engn, UA-61103 Kharkov, Ukraine

[2] IN Frantsevich Inst Mat Sci, UA-03680 Kiev, Ukraine

来源：

LOW TEMPERATURE PHYSICS | 2009年 / 35卷 / 11期

关键词：

SUSCEPTIBILITY; TEMPERATURE; SCB2;

D O I：

10.1063/1.3266916

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The temperature dependences of the magnetic susceptibility chi and its anisotropy Delta chi=chi(parallel to)-chi(perpendicular to) have been measured for hexagonal single crystals of transition-metal dibofides MB2 (M=Sc, Ti, V, Zr, Hf) in the temperature interval 4.2-300 K. It is found that the anisotropy Delta chi is weakly temperature-dependent, a nonmonotonic function of the filling of the hybridized p-d conduction band, and largest for group-IV transition metals. First-principles calculations of the electronic structure of dibofides and the values of the paramagnetic contributions (spin and Van Vleck) to their susceptibility show that the behavior of the magnetic anisotropy is due to the competition between Van Vleck paramagnetism and orbital diamagnetism of the conduction electrons. (C) 2009 American Institute of Physics. [doi: 10.1063/1.3266916]

引用

页码：862 / 868

页数：7

共 50 条

[1] Electronic structure and magnetic properties of transition metal diborides
Grechnev, G.E.
Fedorchenko, A.V.
Logosha, A.V.
Panfilov, A.S.
Svechkarev, I.V.
Filippov, V.B.
Lyashchenko, A.B.
Evdokimova, A.V.
[J]. Journal of Alloys and Compounds, 2009, 481 (1-2): : 75 - 80
[2] Electronic structure and magnetic properties of transition metal diborides
Grechnev, G. E.
Fedorchenko, A. V.
Logosha, A. V.
Panfilov, A. S.
Svechkarev, I. V.
Filippov, V. B.
Lyashchenko, A. B.
Evdokimova, A. V.
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 481 (1-2) : 75 - 80
[3] ELECTRONIC STRUCTURE OF TRANSITION METAL DIBORIDES
CASTAING, J
CAUDRON, R
TOUPANCE, G
COSTA, P
[J]. SOLID STATE COMMUNICATIONS, 1969, 7 (20) : 1453 - &
[4] NUCLEAR MAGNETIC RESONANCE IN TRANSITION-METAL DIBORIDES
SILVER, AH
KUSHIDA, T
[J]. JOURNAL OF CHEMICAL PHYSICS, 1963, 38 (04): : 865 - &
[5] THE ELECTRONIC-STRUCTURE OF THE 1ST-ROW TRANSITION-METAL DIBORIDES
ARMSTRONG, DR
[J]. THEORETICA CHIMICA ACTA, 1983, 64 (02): : 137 - 152
[6] Physical processes of the formation of structure and properties of films of transition-metal diborides
A. A. Goncharov
[J]. The Physics of Metals and Metallography, 2011, 111 : 314 - 324
[7] THE ELECTRONIC-STRUCTURE OF THE 1ST-ROW TRANSITION-METAL DIBORIDES
ARMSTRONG, DR
[J]. JOURNAL OF THE LESS-COMMON METALS, 1981, 82 (1-2): : 357 - 357
[8] Physical processes of the formation of structure and properties of films of transition-metal diborides
Goncharov, A. A.
[J]. PHYSICS OF METALS AND METALLOGRAPHY, 2011, 111 (03): : 314 - 324
[9] Electronic structure and magnetic properties of substitutional transition-metal atoms in GaN nanotubes
Zhang Min
Shi Jun-Jie
[J]. CHINESE PHYSICS B, 2014, 23 (01)
[10] Electronic structure and magnetic properties of dilute Cr alloys with transition-metal impurities
Mishra, S. N.
[J]. PHYSICAL REVIEW B, 2008, 77 (22):

← 1 2 3 4 5 →