Au/α-Fe2O3 catalyst for water-gas shift reaction prepared by deposition-precipitation

被引:136
|
作者
Andreeva, D
Tabakova, T
Idakiev, V
Christov, P
Giovanoli, R
机构
[1] Bulgarian Acad Sci, Inst Catalysis, BU-1113 Sofia, Bulgaria
[2] Univ Bern, CH-3000 Bern 9, Switzerland
关键词
Au/alpha-Fe2O3; preparation; WGS reaction;
D O I
10.1016/S0926-860X(97)00302-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A modified version of the preparation methods for the synthesis of highly-active Au/alpha-Fe2O3 catalysts for WGS reaction has been proposed. The results obtained show that gold dispersion is highly preserved and prevents cluster formation. On the other hand, a major part of gold remains on the surface, thus being accessible to catalysis. As a result of the preparation technique, it seems that the interaction between gold and support is weaker and, likely, more favourable for catalysis. This study demonstrates that a specific approach to preparation of catalysts of optimum structure and texture is crucial for high-catalytic activity. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:9 / 14
页数:6
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