Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents

被引：3
|
作者：
Destarac, M
Charmot, D
Franck, X
Zard, SZ
机构：
[1] Rhodia Rech, F-93308 Aubervilliers, France
[2] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France
[3] Ecole Polytech, Dept Organ Synth, F-91128 Palaiseau, France
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2000年 / 21卷 / 15期
关键词：
D O I：
10.1002/1521-3927(20001001)21:15<1035::AID-MARC1035>3.0.CO;2-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Control of the radical polymerization acrylates, styrene and vinyl acetate has been achieved using novel dithiocarbamates as reversible addition-fragmentation chain transfer agents. The key parameter for the control with N,N-disubstituted (A) or cyclic (B) dithiocarbamates was round to be the conjugation of the lone of pair of electrons of the nitrogen atom with carbonyl or aromatic groups.
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页码：1035 / 1039
页数：5
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