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Pressure-Induced Effects in Organic-Inorganic Hybrid Perovskites
被引:90
|作者:
Postorino, Paolo
[1
]
Malavasi, Lorenzo
[2
,3
]
机构:
[1] Univ Rome Sapienza, Phys Dept, I-00185 Rome, Italy
[2] Univ Pavia, Chem Dept, I-27100 Pavia, Italy
[3] INSTM, I-27100 Pavia, Italy
来源:
关键词:
FORMAMIDINIUM LEAD IODIDE;
VISIBLE-LIGHT RESPONSE;
ELECTRONIC-TRANSITIONS;
HALIDE PEROVSKITES;
PHASE-TRANSITIONS;
METHYLAMMONIUM;
AMORPHIZATION;
STABILIZATION;
TRANSPORT;
D O I:
10.1021/acs.jpclett.7b00347
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
In this Perspective, we provide an overview of the pressure induced effects on hybrid organic inorganic perovskite for photovoltaics applications. It is shown that a fine-tuning of the most relevant photovoltaic properties, including band gap and carrier lifetime, is indeed possible by applying pressure over a rather small range and that such phenomena closely correlate with pressure-induced structural changes. High-pressure research can be used to search for new materials since the high-pressure structural configuration can be used as a model for tailoring ambient pressure compounds under proper chemical substitution, and the band gap tuning and enhancement of carrier lifetime with applied pressures can be a guide to design new hybrid perovskites with desired optical properties as a function of structural parameters.
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页码:2613 / 2622
页数:10
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