2,9-Bis(trichloromethyl)-1,10-phenanthroline

被引：1
|
作者：
Fun, Hoong-Kun [1 ]
Chantrapromma, Suchada [2 ]
Maity, Annada C. [3 ]
Goswami, Shyamaprosad [3 ]
机构：
[1] Univ Sains Malaysia, Xray Crystallog Unit, Sch Phys, George Town 11800, Malaysia
[2] Prince Songkla Univ, Crystal Mat Res Unit, Dept Chem, Fac Sci, Hat Yai 90112, Songkhla, Thailand
[3] Bengal Engn & Sci Univ, Dept Chem, Sibpur 711103, Howrah, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
X-RAY; DIFFRACTION;
D O I：
10.1107/S1600536810002035
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, C(14)H(6)Cl(6)N(2), contains two crystallographically independent molecules, each of which is slightly twisted from planarity. The dihedral angles between the central ring and the two outer rings are 3.81 (7) and 4.30 (7)degrees in one molecule, and 4.13 (8) and 4.10 (7)degrees in the other. In the crystal structure, molecules are interlinked by C-Cl center dot center dot center dot Cl interactions into sheets parallel to the ac plane. These sheets are stacked along the b axis in such a way that the molecules are antiparallel; they are further connected into a supramolecular network. There are no classical hydrogen bonds. C center dot center dot center dot Cl [3.637 (2) angstrom], Cl center dot center dot center dot Cl [3.5639 (5)-3.6807 (8) angstrom] and Cl center dot center dot center dot N [3.3802 (15)-3.4093 (15) angstrom] short contacts and pi-pi interactions, with centroid-centroid distances in the range 3.5868 (9)-3.7844 (9) angstrom, are observed.
引用
收藏
页码：O424 / U3053
页数：12
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