Selective Oxidation of Glycosyl Sulfides to Sulfoxides with Sodium Hypochlorite and Catalyzed by Metalloporphyrins

被引：7
|
作者：
Huang, Jian-Ying [1 ]
Li, Shi-Jun [2 ]
Wang, Yan-Guang [3 ]
机构：
[1] Zhejiang Gongshang Univ, Dept Appl Chem, Hangzhou 310035, Zhejiang, Peoples R China
[2] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 310027, Peoples R China
[3] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
JOURNAL OF CARBOHYDRATE CHEMISTRY | 2010年 / 29卷 / 03期
关键词：
Oxidation; Glycosyl sulfide; Glycosyl sulfoxide; Sodium hypochlorite; Metalloporphyrin;
D O I：
10.1080/07328303.2010.483041
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
An efficient and selective method for oxidation of glycosyl sulfides to the corresponding glycosyl sulfoxides with metalloporphyrins as catalysts and sodium hypochlorite as oxidant was achieved under mild conditions. High chemoselectivity and diastereomeric excesses were obtained. Both acid-labile protected groups and carbon-carbon double bonds of allyl groups tolerated under these conditions.
引用
收藏
页码：142 / 153
页数：12
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