A quasi-cyclic structure of tetraphenyldithioimidodiphosphinato (triphenylphosphine)-gold(I), Ph3P•Au(SPh2PNPPh2S), involving Au•••S secondary bonds

被引：0

作者：

Haiduc, I ^{[1
]}

Fischer, A

Edelmann, FT

机构：

[1] Univ Babes Bolyai, Fac Chem, RO-3400 Cluj Napoca, Romania

[2] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany

来源：

REVUE ROUMAINE DE CHIMIE | 1999年 / 44卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mixed tetraphenyldithioimidodiphosphinato (triphenylphosphine)-gold(I) complex, Ph3P . Au(SPh2PNPPh2), displays an asymmetric quasi-cyclic structure with two non-equivalent gold-sulfur bonds [primary Au-S 2.3355(9) Angstrom and secondary Au ... S 3.0429(10) Angstrom], differing from the metallacycle structure of the known gold(III) derivative AuCl2(SPh2PNPPh2) and of the copper(I) congener, Ph3P . Cu(SPh2PNPPh2), which contain symmetrical rings AuS2P2N and CuS2P2N, respectively (with Au-S 2.314 and 2.303 Angstrom, and Cu-S 2.215 and 2.258 Angstrom).

引用

页码：805 / 809

页数：5

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