Synthesis, physico-chemical and thermal characteristics of seven and ten coordinated complexes of trivalent lanthanides derived from 4[N-(cinnamalidene)amino]antipyrine semicarbazone and diphenyl sulfoxide

被引：6

作者：

Agarwal, R. K. ^{[1
]}

Prakash, B. ^{[1
]}

Kumar, V. ^{[1
]}

Khan, A. Aslam ^{[1
]}

机构：

[1] Lajpat Rai Postgrad Coll, Dept Chem, Sahibabad Ghaziabad 201005, India

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2007年 / 4卷 / 01期

关键词：

lanthanide(III); complexes; 4[N-cinnamalidene)amino]antipyrine semicarbazone; diphenyl sulfoxide;

D O I：

10.1007/BF03245809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In present studies a new series of twenty four complexes of seven and ten coordinated compounds derived from 4[N-cinnamalidene) amino] antipyrine semicarbazone (CAAPS) as primary ligand and diphenyl sulfoxide (DPSO) as secondary ligand has been reported. All the complexes have the general composition LnX(3).n(CAAPS).DPSO (Ln = La, Pr, Nd, Sm, Gd, Tb, Dy or Ho, X = NCS or ClO4, n = 2, X = NO3, n = 1). The compounds have been characterized by elemental analysis, molar conductance, magnetic susceptibility, infrared and electronic spectra. Thermal characteristics were also reported. Based on the data appropriate structures are assigned for these complexes.

引用

页码：114 / 125

页数：12

共 13 条

[1] Synthesis, physico-chemical and thermal characteristics of seven and ten coordinated complexes of trivalent lanthanides derived from 4[N-(cinnamalidene)amino]antipyrine semicarbazone and diphenyl sulfoxide
R. K. Agarwal
B. Prakash
V. Kumar
A. Aslam Khan
[J]. Journal of the Iranian Chemical Society, 2007, 4 : 114 - 125
[2] Synthesis and characterization of some hexa and nona-coordinated complexes of trivalent lanthanides(III) derived from 4[N-(4′-dimethylaminobenzalidene)amino] antipyrine semicarbazone
Chakraborti, I
Goel, N
[J]. ASIAN JOURNAL OF CHEMISTRY, 2003, 15 (02) : 679 - 686
[3] Synthesis, Characterization and Biological Evaluation of a Novel Series of Mixed Ligand Complexes of Lanthanides(III) with 4[N-(Furfural)amino]antipyrine Semicarbazone as Primary Ligand and Diphenyl Sulfoxide as Secondary Ligand
Prasad, S.
Agarwal, R. K.
Kumar, A.
[J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2011, 8 (03) : 825 - 839
[4] Synthesis, characterization and biological evaluation of a novel series of mixed ligand complexes of lanthanides(III) with 4[N-(furfural)amino]antipyrine semicarbazone as primary ligand and diphenyl sulfoxide as secondary ligand
S. Prasad
R. K. Agarwal
A. Kumar
[J]. Journal of the Iranian Chemical Society, 2011, 8 : 825 - 839
[5] Synthesis and characterization of some lanthanide(III) chloro complexes derived from 4[N-(4′-hydroxy-3′-methoxybenzalidene) amino] antipyrine semicarbazone and 4[N-(3′,4′,5′-trimethoxybenzalidene) amino]antipyrine semicarbazone
Agarwal, RK
Prasad, S
Chakraborti, I
[J]. IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2004, 23 (02): : 113 - 119
[6] Synthesis and physico-chemical investigations of some seven coordinated complexes of lanthanides(III) chloride derived from hydrazones of isonicotinic acid hydrazide
Khan, Azhar Aslam
Sharma, Narendra K.
[J]. ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (07) : 4969 - 4979
[7] SYNTHESIS AND STRUCTURAL INVESTIGATIONS OF SOME 5-COORDINATED OXOVANADIUM(IV) COMPLEXES OF 4[N-(BENZYLIDENE)AMINO] ANTIPYRINE SEMICARBAZONE
CHAKRABORTI, I
MANGLIK, AK
[J]. ASIAN JOURNAL OF CHEMISTRY, 1995, 7 (04) : 903 - 906
[8] Synthesis and characterization of oxovanadium(IV) coordination compounds derived from 4[N-(4-hydroxy-3-methoxy benzalidene) amino] antipyrine semicarbazone and 4[N-(3,4,5-trimethoxybenzalidene) amino] antipyrine semicarbazone
Singh, L
Singh, U
Singh, UP
[J]. ASIAN JOURNAL OF CHEMISTRY, 2001, 13 (04) : 1427 - 1434
[9] Synthesis, spectral and thermal characteristics of some ten coordinated complexes of dioxouranium(VI) derived from semicarbazones as primary ligand and diphenyl sulfoxide as secondary ligand
Agarwal, Ram K.
Prasad, Surendra
[J]. TURKISH JOURNAL OF CHEMISTRY, 2006, 30 (05) : 553 - 562
[10] Synthesis and magneto-spectral investigations of some six and nine coordinated complexes of lanthanides(III) derived from 4[N-(2′-hydroxy-1′-naphthalidene) amino]antipyrinethiosemicarbazone
R. K. Agarwal
R. K. Garg
S. K. Sindhu
[J]. Journal of the Iranian Chemical Society, 2005, 2 : 203 - 211

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