Synthesis, structure and magnetic property of a copper(II)-cobalt(II) heteronuclear complex with Schiff base ligand

被引:1
|
作者
Tan, Yuye [1 ]
Huang, Junjie [1 ]
Lu, Hui [1 ]
Chi, Tao [2 ,3 ]
Sun, Jianhua [1 ]
机构
[1] Jiangsu Univ Technol, Sch Chem & Environm Engn, Changzhou 213001, Peoples R China
[2] Shanghai Ocean Univ, Coll Informat Technol, Shanghai, Peoples R China
[3] Minist Agr, Key Lab Fisheries Informat, Shanghai, Peoples R China
基金
中国国家自然科学基金;
关键词
Schiff base; heteronuclear; crystal structure; magnetic property; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; BEHAVIOR; COBALT; SEPARATION; SERIES; CU;
D O I
10.1080/24701556.2019.1661444
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new heteronuclear complex [LCuCo(NO3)(2)] (1) (H2L = N,N'-ethylenebis [3-methoxysalicylaldimine]) was synthesized and structurally characterized. The complex consists of a dimer skeleton which composed of a slightly distorted square-planar copper and pentacoordinated cobalt ions. The magnetic properties reveal the presence of antiferromagnetic interactions between the metal centers linked by double phenoxo-bridging.
引用
收藏
页码:110 / 113
页数:4
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