Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks

被引：16

作者：

Coupry, D. E. ^{[1
]}

Butson, J. ^{[2
]}

Petkov, P. S. ^{[1
]}

Saunders, M. ^{[3
]}

O'Donnell, K. ^{[2
]}

Kim, H. ^{[4
]}

Buckley, C. ^{[2
]}

Addicoat, M. ^{[1
]}

Heine, T. ^{[1
,5
]}

Szilagyi, P. A. ^{[2
,6
]}

机构：

[1] Jacobs Univ Bremen, Dept Phys & Earth Sci, Campus Ring 1, D-28759 Bremen, Germany

[2] Curtin Univ, Dept Phys Astron & Med Radiat Sci, GPO Box U1987, Perth, WA 6845, Australia

[3] Ctr Microscopy Characterisat & Anal, M010, Perth, WA 6009, Australia

[4] Natl Inst Adv Ind Sci & Technol, Cent 5-2,1-1-1 Higashi, Tsukuba, Ibaraki 3058565, Japan

[5] Univ Leipzig, Fak Chem & Mineral, Wilhelm Ostwald Inst Phys & Theoret Chem, Linnestr 2, D-04103 Leipzig, Germany

[6] Univ Greenwich, Dept Pharmaceut Chem & Environm Sci, Medway Campus, Chatham ME4 4TB, Kent, England

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 29期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会; 澳大利亚研究理事会;

关键词：

DENSITY-FUNCTIONAL THEORY; ACCURATE DESCRIPTION; SELECTIVE OXIDATION; HYDROGEN SPILLOVER; CATALYSTS; CLUSTERS; NANOPARTICLES; LUMINESCENT; IRIDIUM; RHODIUM;

D O I：

10.1039/c6cc00659k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combined theoretical and experimental approach demonstrates that nanocluster embedment into the pores of metal-organic frameworks (MOF) may be influenced by the chemical functionalisation of the MOF. Furthermore, this results in the surface functionalisation of the embedded nanoclusters, highlighting the potential of MOF scaffolds for the design and synthesis of novel functional materials.

引用

页码：5175 / 5178

页数：4

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