Rhodium-catalyzed rapid synthesis of substituted phenols from cyclobutenones and alkynes or alkenes via C-C bond cleavage

被引：43
|
作者：
Kondo, Teruyuki [1 ]
Niimi, Masatsugu [1 ]
Nomura, Masato [1 ]
Wada, Kenji [1 ]
Mitsudo, Take-aki [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 16期
基金：
日本学术振兴会;
关键词：
rhodium; catalyst; phenol; cyclobutenone; C-C bond cleavage;
D O I：
10.1016/j.tetlet.2007.02.091
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel rhodium-catalyzed synthesis of substituted phenols by the ring-opening reaction of cyclobutenones with alkynes as well as electron-deficient alkenes has been developed. Both reactions involve C-C bond cleavage of cyclobutenones, and an (eta(4)- vinylketene)rhodium complex rather than a rhodacyclopenterione is considered to be a key intermediate. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2837 / 2839
页数：3
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