Syntheses of Chiral Ferrocenophanes and Their Application to Asymmetric Catalysis

被引：16

作者：

Zhang, Qiying ^{[1
]}

Cui, Xiuling ^{[1
]}

Chen, Lianmei ^{[1
]}

Liu, Haitao ^{[1
]}

Wu, Yangjie ^{[1
]}

机构：

[1] Zhengzhou Univ, Henan Key Lab Chem Biol & Organ Chem, Key Lab Appl Chem Henan Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 2014卷 / 35期

基金：

中国国家自然科学基金;

关键词：

Sandwich complexes; Organocatalysis; Asymmetric synthesis; Oxidative coupling; Michael addition; ORGANOCATALYTIC MICHAEL REACTIONS; RING-OPENING POLYMERIZATION; STRUCTURAL-CHARACTERIZATION; ENANTIOSELECTIVE SYNTHESIS; ALDEHYDES; LIGANDS; PYRROLIDINE; DERIVATIVES; ACTIVATION; COMPLEXES;

D O I：

10.1002/ejoc.201402985

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Substituted 2-aza-[3]-ferrocenophanes were easily synthesized from 1,1-ferrocenedicarbaldehyde and aliphatic amines in high yields. One of the ferrocenophanes served as a ligand for the copper-catalyzed oxidative coupling of 2-naphthol derivatives to give the products in good yields with up to 92% ee, and it also efficiently catalyzed the asymmetric Michael addition reaction as an organocatalyst.

引用

页码：7823 / 7829

页数：7

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