Synthesis and structure of bis(triphenylphosphino) dichlorohydroxooxorhenium(V)

被引：1
|
作者：
Gerber, Thomas I. A.
Mayer, Peter
Tshentu, Zenixole R.
机构：
[1] Nelson Mandela Metropolitan Univ, Dept Chem, ZA-6031 Port Elizabeth, South Africa
[2] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 06期
关键词：
rhenium(V); oxo-hydroxo; crystal structure;
D O I：
10.1080/00958970600853499
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of equimolar amounts of trans-[ReOCl3(PPh3)(2)] and 2-aminobenzimidazole in acetone containing 1% water led to the isolation of trans-[ReO(OH)Cl-2(PPh3)(2)]. The product has been characterized by infrared spectroscopy and X-ray crystallography. The hydroxo group is coordinated trans to the oxo group, with the respective bond lengths Re-OH 1.911(3) and Re=O=1.815(3) angstrom.
引用
收藏
页码：641 / 645
页数：5
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