Synthesis and optical properties of fluorinated poly(arylene ether phosphine oxide)s

被引：24
|
作者：
Kim, JP [1 ]
Kang, JW [1 ]
Kim, JJ [1 ]
Lee, JS [1 ]
机构：
[1] Kwangju Inst Sci & Technol, Dept Mat Sci & Engn, Bukgu, Kwangju 500712, South Korea
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2003年 / 41卷 / 10期
关键词：
halogenated; poly(arylene ether phosphine oxide); refractive index; optical loss; step-growth polymerization;
D O I：
10.1002/pola.10694
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Fluorinated dihydroxy phosphine oxide monomers were synthesized via chlorination, Grignard, and demethylation techniques. The prepared monomer was successfully polymerized with each of the three perfluorinated monomers (decafluoro-biphenyl, decafluorobenzophenone, and pentafluorophenylsulfide) by nucleophilic aromatic substitution. The average molecular weight ranged between 7800 and 14,900 g/mol. The glass-transition temperatures of the polymers were registered in the range of 185-235 degreesC, and all the polymers exhibited high thermal stability up to 326-408 degreesC. The results of the refractive-index measurements indicated control of the refractive index between 1.5181 and 1.5536 and an optical loss of 0.53 dB/cm at 1550 nm. (C) 2003 Wiley Periodicals,
引用
收藏
页码：1497 / 1503
页数：7
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