Photochemical evolution of palladium nanoparticles in Triton X-100 and its application as catalyst for degradation of acridine orange

被引:0
|
作者
Nath, Sudip [1 ]
Praharaj, Snigdhamayee [1 ]
Panigrahi, Sudipa [1 ]
Basu, Soumen [1 ]
Pal, Tarasankar [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India
来源
CURRENT SCIENCE | 2007年 / 92卷 / 06期
关键词
catalyst; nanoparticle; palladium; Triton X-100; UV-irradiation;
D O I
暂无
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
A solution phase UV-photoactivation technique has been reported to prepare palladium nanoparticles. Aqueous H2PdCl4 solution was irradiated under UV-light (similar to 365 nm, 340 lux) in a nonionic surfactant solution to produce Pd(0) nanoparticles. The particles generated in this method are stable, spherical and small (5-10 nm) with a tight size distribution. Catalytic activity of the photoproduced palladium nanoparticles has been substantiated through photodecolorization of aqueous acridine orange solution. It has been found that the photoproduced palladium nanoparticles have a profound influence on the reaction rate and the rate varies linearly with nanoparticle concentration.
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页码:786 / 790
页数:5
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