Studies on Dehydrogenation of Ethane in the Presence of CO2 over Octahedral Molecular Sieve (OMS-2) Catalysts

被引：26
|
作者：
Jin, Lei [1 ]
Reutenauer, Justin [1 ]
Opembe, Naftali [1 ]
Lai, Monique [1 ]
Martenak, Daniel J. [2 ]
Han, Scott [2 ]
Suib, Steven L. [1 ]
机构：
[1] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA
[2] Rohm & Haas Co, Spring House, PA 19477 USA
来源：
CHEMCATCHEM | 2009年 / 1卷 / 04期
关键词：
carbon dioxide; carbonylation; dehydrogenation; green chemistry; manganese; SOL-GEL SYNTHESIS; MANGANESE OXIDE; OXIDATIVE DEHYDROGENATION; CARBON-DIOXIDE; CRYPTOMELANE; ETHYLENE; DECOMPOSITION; PERFORMANCE; ALCOHOLS;
D O I：
10.1002/cctc.200900149
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A breath of fresh air: The octahedral molecular sieve (OMS-2) catalyst shows outstanding catalytic activity, selectivity, and stability in the dehydrogenation of ethane into ethylene in the presence of CO2. This process can be extended for other alkanes, giving an ideal feedstock for any process involving alkene carbonylation, as a greenhouse gas, CO2, can be recycled. © 2009 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.
引用
收藏
页码：441 / 444
页数：4
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