Transition metal-catalyzed carboxylation of unsaturated substrates with CO2

被引：171

作者：

Yan, Si-Shun ^{[1
]}

Fu, Qiang ^{[1
,2
]}

Liao, Li-Li ^{[1
]}

Sun, Guo-Quan ^{[1
]}

Ye, Jian-Heng ^{[1
]}

Gong, Li ^{[1
]}

Bo-Xue, Yin-Zi ^{[1
]}

Yu, Da-Gang ^{[1
,3
]}

机构：

[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China

[2] Southwest Med Univ, Sch Pharm, Luzhou 646000, Peoples R China

[3] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2018年 / 374卷

基金：

中国国家自然科学基金;

关键词：

Carbon dioxide; Carboxylation; Unsaturated substrates; Transition metal catalysis; NICKEL(0)-MEDIATED SEQUENTIAL ADDITION; AMINO-ACID-DERIVATIVES; CARBON-DIOXIDE; REDUCTIVE CARBOXYLATION; REGIOSELECTIVE HYDROCARBOXYLATION; ALKYLATIVE CARBOXYLATION; VISIBLE-LIGHT; DIALKYLZINC REAGENTS; PALLADIUM COMPLEXES; TERMINAL ALKYNES;

D O I：

10.1016/j.ccr.2018.07.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The utilization of CO2 as a C1 building block for the synthesis of valuable chemicals is of great importance. The transition metal-catalyzed carboxylation of unsaturated substrates with CO2 has proved to be an effective and versatile strategy for the incorporation of CO2 in organic substrates with unsaturated bonds. Different kinds of carboxylation reactions with CO2 have provided a direct access to a myriad of functionalized carboxylic acids and derivatives. This review focuses on carboxylation of unsaturated substrates with CO2 via transition metal catalysis. Various kinds of carboxylations with different catalytic systems are discussed. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：439 / 463

页数：25

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