Improved preparation of indenyl molybdenum(II) and tungsten(II) compounds

被引：2
|
作者：
Honzicek, Jan [1 ,2 ]
Mukhopadhyay, Abhik [3 ]
Romao, Carlos C. [1 ]
机构：
[1] Univ Nova Lisboa, Inst Tecnol Quim & Biol, EAN, P-2780157 Oeiras, Portugal
[2] Univ Pardubice, Dept Gen & Inorgan Chem, Fac Chem Technol, Pardubice 53210, Czech Republic
[3] FCT UNL, REQUIMTE CQFB, Dept Quim, P-2829516 Monte De Caparica, Portugal
来源：
INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 07期
关键词：
Metallocene; Indenyl complexes; Molybdenum; Tungsten; X-ray diffraction; OLEFIN EPOXIDATION; COMPLEXES; ORGANOMOLYBDENUM; CATALYSTS; ALLYL;
D O I：
10.1016/j.ica.2010.01.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Oxidative addition of 1-bromo-1H-indene to [Mo(CO)(3)(NCMe)(3)] and [W(CO)(3)(NCEt)(3)] is a suitable method for preparation of the indenyl compounds [IndMo(CO)(3)Br] and [IndW(CO)(3)Br], respectively. These products were fully characterised using spectroscopic methods. Structure of [ IndW( CO) 3Br] was determined by single crystal X-ray diffraction analysis. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1601 / 1603
页数：3
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