Comparison of Biological Efficiency Assessment Methods and Their Application to Full-Scale Biogas Plants

For calculation of biological efficiency of a biogas plant (BP), it is required to determine the specific methane potential (SMP) of the substrate. A study comparing available methods for determination of SMP and the comparison with data of full-scale BPs is missing but necessary according to the differences in process conditions between both. Firstly, mass and mass associated energy balances of 33 full-scale BPs were calculated and evaluated. The results show plausible data for only 55% of the investigated BPs. Furthermore, conversion and yield efficiencies were calculated according to six different methods for SMP determination. The results show a correlation between the measured on-site specific methane yield and the calculated SMP by methods based on biological degradability. However, these methods underestimate the SMP. Calculated SMPs based on calorific values are higher, but less sensitive. A combination of biochemical and energetical methods is a promising approach to evaluate the efficiency.