Poly(a)morphic portrait of the electrical double layer in ionic liquids

被引:62
|
作者
Ivanistsev, V. [1 ]
O'Connor, S. [1 ]
Fedorov, M. V. [1 ]
机构
[1] Univ Strathclyde, SUPA, Dept Phys, Glasgow G4 0NG, Lanark, Scotland
基金
英国工程与自然科学研究理事会;
关键词
Ionic liquids; Electrical double layer; Molecular simulations; INTERFACE; CAPACITANCE; TRANSITION;
D O I
10.1016/j.elecom.2014.08.014
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this paper we present a unified view on charge-driven structural transitions in the electrical double layer in ionic liquids and summarise molecular-scale mechanisms of the ionic liquid structural response to the surface charge. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:61 / 64
页数:4
相关论文
共 50 条
  • [1] Water in the Electrical Double Layer of Ionic Liquids on Graphene
    Zheng, Qianlu
    Goodwin, Zachary A. H.
    Gopalakrishnan, Varun
    Hoane, Alexis G.
    Han, Mengwei
    Zhang, Ruixian
    Hawthorne, Nathaniel
    Batteas, James D.
    Gewirth, Andrew A.
    Espinosa-Marzal, Rosa M.
    [J]. ACS NANO, 2023, 17 (10) : 9347 - 9360
  • [2] Self-assembly in the electrical double layer of ionic liquids
    Perkin, Susan
    Crowhurst, Lorna
    Niedermeyer, Heiko
    Welton, Tom
    Smith, Alexander M.
    Gosvami, Nitya Nand
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (23) : 6572 - 6574
  • [3] Restructuring of the electrical double layer in ionic liquids upon charging
    Ivanistsev, V.
    Kirchner, K.
    Kirchner, T.
    Fedorov, M. V.
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2015, 27 (10)
  • [4] Cracking Ion Pairs in the Electrical Double Layer of Ionic Liquids
    Goodwin, Zachary A. H.
    Kornyshev, Alexei A.
    [J]. ELECTROCHIMICA ACTA, 2022, 434
  • [5] Gelation, clustering, and crowding in the electrical double layer of ionic liquids
    Goodwin, Zachary A. H.
    McEldrew, Michael
    de Souza, J. Pedro
    Bazant, Martin Z. Z.
    Kornyshev, Alexei A. A.
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2022, 157 (09):
  • [6] Molecular dynamics simulation of the electrical double layer in ionic liquids
    Kislenko, S. A.
    Amirov, R. H.
    Samoylov, I. S.
    [J]. 7TH INTERNATIONAL CONFERENCE ON APPLIED ELECTROSTATICS (ICAES-2012), 2013, 418
  • [7] Electrical Double Layer in Mixtures of Room-Temperature Ionic Liquids
    Alam, Muhammad Tanzirul
    Islam, Md Mominul
    Okajima, Takeyoshi
    Ohsaka, Takeo
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (16): : 6596 - 6601
  • [8] Electrical Double Layer of Linear Tricationic Ionic Liquids at Graphite Electrode
    Li, Dan-Dan
    Yang, Yan-Ru
    Wang, Xiao-Dong
    Feng, Guang
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2020, 124 (29): : 15723 - 15729
  • [9] Towards understanding the structure and capacitance of electrical double layer in ionic liquids
    Fedorov, Maxim V.
    Kornyshev, Alexei A.
    [J]. ELECTROCHIMICA ACTA, 2008, 53 (23) : 6835 - 6840
  • [10] THE DIFFUSE DOUBLE LAYER IN IONIC LIQUIDS
    Fawcett, W. Ronald
    Ryan, Peter J.
    [J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2009, 74 (11-12) : 1665 - 1674