Mesoscopic organization in ionic liquids

被引：27
|
作者：
Russina, Olga [1 ]
Lo Celso, Fabrizio [2 ]
Plechkova, Natalia [3 ]
Jafta, Charl J. [4 ]
Appetecchi, Giovanni Battista [5 ]
Triolo, Alessandro [6 ]
机构：
[1] Univ Roma Sapienza, Dipartimento Chim, Rome, Italy
[2] Univ Palermo, Dipartimento Fis & Chim, Palermo, Italy
[3] Queens Univ Belfast, QUILL, Stranmillis Rd, Belfast, Antrim, North Ireland
[4] Helmholtz Zentrum Berlin Mat & Energie GmbH, Hahn Meitner Pl 1, Berlin, Germany
[5] ENEA, Dept SSPT PROMAS MATPRO, I-00123 Rome, Italy
[6] CNR, Lab Liquidi Ion, Ist Struttura Mat, Rome, Italy
来源：
TOPICS IN CURRENT CHEMISTRY | 2017年 / 375卷 / 03期
关键词：
Ionic liquid; X-ray and neutron scattering; Molecular dynamics simulation; Mesoscopic and microscopic structure; X-RAY-SCATTERING; HYDROGEN-BONDED INTERACTIONS; ETHYLAMMONIUM NITRATE; PHYSICOCHEMICAL PROPERTIES; CATION SYMMETRY; NEUTRON-SCATTERING; CRITICAL-POINT; N-OCTANOL; TEMPERATURE; DYNAMICS;
D O I：
10.1007/s41061-017-0147-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We discuss some published results and provide new observations concerning the high level of structural complexity that lies behind the nanoscale correlations in ionic liquids (ILs) and their mixtures with molecular liquids. It turns out that this organization is a consequence of the hierarchical construction on both spatial (from (a) over circle ngstrom to several nanometer) and temporal (from fraction of picosecond to hundreds of nanosecond) scales, which requires joint use of experimental and computational tools.
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页数：17
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