High efficiency of dye-sensitized solar cells based on metal-free indoline dyes

被引:1130
|
作者
Horiuchi, T
Miura, H
Sumioka, K
Uchida, S
机构
[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
[2] Mitsubishi Paper Mills Co Ltd, Corp Res Ctr, Technol Res Lab, Tsukuba, Ibaraki 3004247, Japan
[3] Mitsubishi Paper Mills Co Ltd, Corp Res Ctr, Dev Lab, Nagaokakyo, Kyoto 6178666, Japan
关键词
D O I
10.1021/ja0488277
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We now report metal-free organic dyes having a new type of indoline structure, which exhibits high efficiencies in dye-sensitized solar cells. The solar energy to current conversion efficiencies with the new indoline dye was 6.51%. Under the same conditions, the N3 dye was 7.89% and the N719 dye was 8.26%. The new indoline dye was optimized for the amount of 4-tert-butyl pyridine in the electrolyte and cholic acid as a coadsorbent. Subsequently, the solar energy to current conversion efficiencies reached 8.00%. This value was the highest obtained efficiency for dye-sensitized solar cells based on metal-free organic dyes without an antireflection layer. Copyright © 2004 American Chemical Society.
引用
收藏
页码:12218 / 12219
页数:2
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