Synthesis and Single Crystal Structures of N-Substituted Benzamides and Their Chemoselective Selenation/Reduction Derivatives

被引:1
|
作者
Hua, Guoxiong [1 ]
Carpenter-Warren, Cameron L. [1 ]
Cordes, David B. [1 ]
Slawin, Alexandra M. Z. [1 ]
Woollins, J. Derek [1 ,2 ]
机构
[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Khalifa Univ, Dept Chem, Abu Dhabi 127788, U Arab Emirates
来源
MOLECULES | 2021年 / 26卷 / 08期
关键词
N-Substituted Benzamides; Woollins’ reagent; selenation reagent; reduction reagent; single crystal X-ray structures; HETEROCYCLES; CHEMISTRY; AGENTS;
D O I
10.3390/molecules26082367
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A series of N-aryl-N-(2-oxo-2-arylethyl) benzamides and cinnamides has been prepared. The reaction of the benzamides with Woollins' reagent, a highly efficient chemoselective selenation/reduction reagent, gave the corresponding N-aryl-N-(arylenethyl) benzoselenoamides in good yields. Five representative single crystal X-ray structures are discussed.
引用
收藏
页数:10
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