Exploring the limits of 73Ge solid-state NMR spectroscopy at ultrahigh magnetic field

被引：16
|
作者：
Sutrisno, Andre [1 ]
Hanson, Margaret A. [1 ]
Rupar, Paul A. [1 ]
Terskikh, Victor V. [2 ]
Baines, Kim M. [1 ]
Huang, Yining [1 ]
机构：
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
[2] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 16期
基金：
加拿大创新基金会; 加拿大自然科学与工程研究理事会;
关键词：
INTEGER QUADRUPOLAR NUCLEI; ORGANOGERMANIUM COMPOUNDS; SIGNAL ENHANCEMENT; SPECTRA; TENSORS; CASTEP; PULSES; QCPMG;
D O I：
10.1039/b926071d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ultrahigh field natural abundance Ge-73 solid-state wide-line NMR study of germanium dichloride complexed with 1,4-dioxane and tetraphenylgermane yields the largest Ge-73 quadrupolar coupling constant determined by NMR spectroscopy to date and the first direct observation of Ge-73 chemical shift anisotropy.
引用
收藏
页码：2817 / 2819
页数：3
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