The effect of meso-substituents in porphyrins on the emissive power of ytterbium ions in their porphyrin complexes

被引：0
|
作者：
Korovin, YV
Kuz'min, VE
Rusakova, NV
Zhilina, ZI
Vodzinsky, SV
Yudanova, IV
机构：
[1] Natl Acad Sci Ukraine, Bogatsky Physicochem Inst, UA-65080 Odessa, Ukraine
[2] Mechnikov Natl Univ, UA-65026 Odessa, Ukraine
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 48卷 / 03期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The luminescence spectral characteristics of Yb(III) complexes with symmetrically tetrasubstituted porphyrins containing isomer pyridine or quinoline radicals or their carbocyclic analogs in the meso-positions have been determined. Based on the structure-luminescence quantum yield models, variation in the ytterbium 4f-luminescence quantum yield in related porphyrin complexes has been predicted for the first time. The reliability of the theoretical models used is experimentally verified.
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页码：410 / 414
页数：5
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