Room-Temperature Synthesis of Titanium Nitride Using Metastable Nitrogen

被引：4
|
作者：
Anderson, Mark S. [1 ]
机构：
[1] CALTECH, Jet Prop Lab, 4800 Oak Grove Dr, Pasadena, CA 91109 USA
来源：
COATINGS | 2022年 / 12卷 / 08期
基金：
美国国家航空航天局;
关键词：
titanium nitride; plasmonics; metastable nitrogen; surface-enhanced infrared; ENHANCED RAMAN-SPECTROSCOPY; OPEN-AIR; PLASMONICS; STATES;
D O I：
10.3390/coatings12081177
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The room-temperature synthesis of titanium nitride (TiN) is presented using the reaction of metastable nitrogen (MSN) with a titanium metal surface. The MSN is generated in a nitrogen glow discharge with plasma-ion filtering using a commercial direct analysis in real time (DART) source. The MSN is flowed over a titanium substrate at ambient pressure producing TiN surfaces that are ultra-clean and suitable for plasmonic applications. This is demonstrated using surface-enhanced infrared absorption spectroscopy (SEIRA), producing a 100-fold signal enhancement. Nitriding using MSN could find general applications in producing nitrided surfaces with small-scale structures.
引用
收藏
页数：6
相关论文
共 50 条
  • [1] A room-temperature synthesis of titanium nitride hollow spheres
    Chen, LY
    Gu, YL
    Shi, L
    Ma, JH
    Yang, Z
    Qian, YT
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2004, 4 (07) : 896 - 898
  • [2] Titanium nitride room-temperature ferromagnetic nanoparticles
    Morozov, Iu.G.
    Belousova, O.V.
    Belyakov, O.A.
    Parkin, I.P.
    Sathasivam, S.
    Kuznetcov, M.V.
    [J]. Journal of Alloys and Compounds, 2016, 675 : 266 - 276
  • [3] Titanium nitride room-temperature ferromagnetic nanoparticles
    Morozov, Iu. G.
    Belousova, O. V.
    Belyakov, O. A.
    Parkin, I. P.
    Sathasivam, S.
    Kuznetcov, M. V.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 675 : 266 - 276
  • [4] Room-temperature growth of high-purity titanium nitride by laser ablation of titanium in a nitrogen atmosphere
    Gu, HD
    Leung, KM
    Chung, CY
    Han, XD
    [J]. SURFACE & COATINGS TECHNOLOGY, 1998, 110 (03): : 153 - 157
  • [5] Highly Plasmonic Titanium Nitride by Room-Temperature Sputtering
    Chang, Chun-Chieh
    Nogan, John
    Yang, Zu-Po
    Kort-Kamp, Wilton J. M.
    Ross, Willard
    Luk, Ting S.
    Dalvit, Diego A. R.
    Azad, Abul K.
    Chen, Hou-Tong
    [J]. SCIENTIFIC REPORTS, 2019, 9 (1)
  • [6] Highly Plasmonic Titanium Nitride by Room-Temperature Sputtering
    Chun-Chieh Chang
    John Nogan
    Zu-Po Yang
    Wilton J. M. Kort-Kamp
    Willard Ross
    Ting S. Luk
    Diego A. R. Dalvit
    Abul K. Azad
    Hou-Tong Chen
    [J]. Scientific Reports, 9
  • [7] A room-temperature synthesis of nanocrystalline vanadium nitride
    Chen, LY
    Gu, YL
    Shi, L
    Yang, ZH
    Ma, JH
    Qian, YT
    [J]. SOLID STATE COMMUNICATIONS, 2004, 132 (05) : 343 - 346
  • [8] Liquid nitrogen to room-temperature thermometry using niobium nitride thin films
    Bourgeois, Olivier
    Andre, Emmanuel
    Macovei, Cristina
    Chaussy, Jacques
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 2006, 77 (12):
  • [9] Room-temperature ferromagnetism in epitaxial titanium nitride thin films
    Gupta, Siddharth
    Moatti, Adele
    Bhaumik, Anagh
    Sachan, Ritesh
    Narayan, Jagdish
    [J]. ACTA MATERIALIA, 2019, 166 : 221 - 230
  • [10] Rapid Room-Temperature Synthesis of a Metastable Ordered Intermetallic Electrocatalyst
    Wang, Yunfei
    Sun, Du
    Chowdhury, Tomojit
    Wagner, Justine S.
    Kempa, Thomas J.
    Hall, Anthony Shoji
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (06) : 2342 - 2347
12345