Electrocatalytic reduction of proton on polypyrrole coatings onto aluminium modified by the electrochemical cementation process

被引:27
|
作者
Makhloufi, L [1 ]
Hammache, H [1 ]
Saidani, B [1 ]
机构
[1] Univ Bejaia, Fac Sci & Sci Ingn, Dept Genie Proc, Lab Rech Electrochim & Corros, Bejaia 06000, Algeria
关键词
polypyrrole; aluminium; cementation; copper; polymer modified electrode; electrocatalysis;
D O I
10.1016/S1388-2481(00)00081-3
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Strongly adherent and smooth polypyrrole coatings were formed at constant current density on aluminium sheet from aqueous solutions of pyrrole and oxalic acid. A new method (cementation) of formation of modified polypyrrole containing dispersed three-dimensional array of copper is presented. These films were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX). The electrocatalytic effect toward proton reduction was observed on the modified electrode. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:552 / 556
页数:5
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