Transient laser frequency modulation spectroscopy

被引：57

作者：

Hall, GE ^{[1
]}

North, SW

机构：

[1] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY | 2000年 / 51卷

关键词：

radical spectroscopy; kinetics; Doppler spectroscopy; photodissociation dynamics;

D O I：

10.1146/annurev.physchem.51.1.243

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Explicitly time-dependent implementations of optical frequency modulation spectroscopy have been recently applied to a wide range of problems in chemical physics. We provide a brief description of the methodology, with an emphasis on its intrinsic advantages for interrogating transient species. Several examples highlight the application of the technique to high-resolution absorption spectra of free radicals, rate measurements for gas-phase reactions, and Doppler spectroscopy of the gas-phase products of photoinitiated reactions.

引用

页码：243 / 274

页数：34

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