Argon adsorption on Cu3(Benzene-1,3,5-tricarboxylate)2(H2O)3 metal-organic framework

被引：74

作者：

Krungleviciute, V.

Lask, K.

Heroux, L.

Migone, A. D.

Lee, J. -Y.

Li, J.

Skoulidas, A.

机构：

[1] So Illinois Univ, Dept Phys, Carbondale, IL 62901 USA

[2] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

[3] ExxonMobil Res & Engn Co, Fairfax, VA 22037 USA

来源：

LANGMUIR | 2007年 / 23卷 / 06期

关键词：

D O I：

10.1021/la061871a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using volumetric adsorption techniques, we have measured the adsorption of argon on Cu-3(BTC)(2)(H2O)(3), (BTC = benzene-1,3,5-tricarboxylate), a microporous metal-organic framework structure, at temperatures between 66 and 143 K. In addition to the experiments, we have used Grand Canonical Monte Carlo simulations to calculate the adsorption isotherm of argon at 87 K. Our experimental and theoretical results are compared to those of previous studies. The experiments were performed using a high density of points, allowing us to obtain, in detail, the isosteric heat's coverage dependence. Our values from the simulations are in reasonable agreement with those obtained in the experiments.

引用

页码：3106 / 3109

页数：4

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