1/N expansion in the vibron model: Diatomic molecules

被引:8
|
作者
Kuyucak, S [1 ]
Roberts, MK [1 ]
机构
[1] Australian Natl Univ, Res Sch Phys Sci, Dept Theoret Phys, Canberra, ACT 0200, Australia
来源
PHYSICAL REVIEW A | 1998年 / 57卷 / 05期
关键词
D O I
10.1103/PhysRevA.57.3381
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Using angular-momentum-projected mean-field theory, we develop 1/N expansion solutions for the vibron model of diatomic molecules. Analytic expressions of spectroscopic accuracy are derived for rotational vibrational energy levels and for the intensities of transitions among them. The results are used in a systematic study of diatomic molecules in the vibron model with a view to finding appropriate Hamiltonians for a realistic description of rotation-vibration spectra.
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页码:3381 / 3402
页数:22
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