Bi(OTF)3 as novel and efficient catalyst for the stereoselective synthesis of C-pseudoglycals

被引：18

作者：

Yadav, JS ^{[1
]}

Reddy, BVS ^{[1
]}

Reddy, KS ^{[1
]}

Chandraiah, L ^{[1
]}

Sunitha, V ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNTHESIS-STUTTGART | 2004年 / 15期

关键词：

bismuth reagents; glycals; pseudoglycals; C-glycosides;

D O I：

10.1055/s-2004-831187

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

D-Glycals undergo smoothly allylic rearrangement with allyltrimethylsilane and trimethylsilyl cyanide in the presence of catalytic amount of bismuth triflate to afford the corresponding 2,3-unsaturated allyl glycosides and glycosyl cyanides in excellent yields with high alpha-selectivity.

引用

页码：2523 / 2526

页数：4

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