DDQ-Promoted Allylic C-H Phosphorylation of 1,3-Diarylpropenes

被引：21
|
作者：
Chen, Qian [1 ,2 ]
Wen, Chunxiao [1 ]
Wang, Xiaofeng [1 ]
Yu, Guodian [1 ]
Ou, Yingcong [1 ]
Huo, Yanping [1 ]
Zhang, Kun [1 ]
机构：
[1] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China
[2] South China Univ Technol, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 18期
关键词：
phosphorylation; C-H functionalization; DDQ; cross-dehydrogenative coupling; allylphosphonates; DEHYDROGENATIVE-COUPLING REACTIONS; SECONDARY PHOSPHINE OXIDES; MICHAELIS-ARBUZOV; HIGHLY EFFICIENT; METAL-FREE; CROSS; BONDS; COPPER; ARYL; FUNCTIONALIZATION;
D O I：
10.1002/adsc.201800804
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
An efficient allylic C-H phosphorylation has been achieved through the DDQ-promoted cross-dehydrogenative coupling of 1,3-diarylpropenes with P(O)H compounds at room temperature. This method provides a convenient route to allylphosphonates in up to 97% yield with good functional group compatibility.
引用
收藏
页码：3590 / 3594
页数：5
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