Solubility of H2S in (H2O plus piperazine) and in (H2O plus MDEA plus piperazine)

被引：42
|
作者：
Xia, JZ [1 ]
Kamps, APS [1 ]
Maurer, G [1 ]
机构：
[1] Univ Kaiserslautern, Lehrstuhl Tech Thermodynam, D-67653 Kaiserslautern, Germany
来源：
FLUID PHASE EQUILIBRIA | 2003年 / 207卷 / 1-2期
关键词：
gas solubility; sour gas systems; aqueous electrolyte solutions; chemical reacting solutions; hydrogen sulfide; N-methyldiethanolamine; piperazine;
D O I：
10.1016/S0378-3812(02)00331-X
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
New experimental results for the solubility of hydrogen sulfide in aqueous solutions of piperazine are presented for piperazine molalities up to 4 mol/kg of water, temperatures between 313 and 393 K, and pressures up to about 9 MPa. Furthermore, the solubility of hydrogen sulfide was measured in about 2 m MDEA + 2 m piperazine aqueous solutions at 353 K up to about 6 MPa. Considering the new experimental data, a thermodynamic model for describing phase equilibria for the system H2S-methyldiethanolamine-water has been extended allowing for the presence of piperazine. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：23 / 34
页数：12
相关论文
共 50 条
  • [1] Solubility of CO2 in (H2O+piperazine) and in (H2O+MDEA+piperazine)
    Kamps, APS
    Xia, JZ
    Maurer, G
    [J]. AICHE JOURNAL, 2003, 49 (10) : 2662 - 2670
  • [2] ACTIVITY-COEFFICIENTS IN QUATERNARY ELECTROLYTIC SYSTEMS - NACL PLUS NAFORMATE PLUS NAACETATE PLUS H2O, NACL PLUS NAFORMATE PLUS NAPROPIONATE PLUS H2O AND NABR PLUS NAFORMATE PLUS NAACETATE PLUS H2O
    HERNANDEZLUIS, F
    FERNANDEZMERIDA, L
    GALLEGUILLOS, H
    ESTESO, MA
    OOI, KS
    KHOO, SK
    LIM, TK
    [J]. FLUID PHASE EQUILIBRIA, 1995, 109 (01) : 139 - 156
  • [3] Solubility of H2S in H2O plus N-methyldiethanolamine plus (H2SO4 or Na2SO4)
    Anoufrikov, Y
    Kamps, APS
    Rumpf, B
    Smirnova, NA
    Maurer, G
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (10) : 2571 - 2578
  • [4] DENSITIES, VISCOSITIES, AND SURFACE TENSIONS FOR THE 2 TERNARY-SYSTEMS H2O PLUS LIBR PLUS LII AND H2O PLUS LICL PLUS LINO3
    IYOKI, S
    IWASAKI, S
    KURIYAMA, Y
    UEMURA, T
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1993, 38 (02): : 302 - 305
  • [5] MICROWAVE BREAKDOWN IN AIR PLUS H2O
    BANDEL, HW
    MACDONALD, AD
    [J]. JOURNAL OF APPLIED PHYSICS, 1970, 41 (07) : 2903 - +
  • [6] Experimental and modelling of vapour-liquid equilibria of ternary systems {HCOOK plus [Emim]Ac + H2O}, {HCOOK plus [Emim]Br + H2O}, {HCOOK plus [Emim]Cl + H2O}, and {HCOOK + [Emim]NO3 + H2O}
    Ding, Yaqi
    Gao, Neng
    Li, Nian
    Chen, Guangming
    Xuan, Yongmei
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2021, 161 (161):
  • [7] Vapor Pressure Measurement of Ternary Systems LiCl plus [Emim]Cl + H2O, LiBr + [Emim]Cl + H2O, and LiCl plus [Emim]Br + H2O
    Xuan, Yongmei
    Ding, Xianyu
    Gao, Neng
    Ding, Yaqi
    Meng, Xin
    Chen, Guangming
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2019, 64 (06): : 2406 - 2413
  • [8] Vapor Pressure Measurement of Ternary Systems LiBr plus [Emim]l + H2O and LiBr plus [Dmim]l + H2O
    Xuan, Yongmei
    Fang, Kaile
    Duan, Bosheng
    Gao, Neng
    Chen, Guangming
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2020, 65 (02): : 487 - 494
  • [9] Vapor Pressure Measurement of Ternary Systems LiCl plus [Emim]l + H2O and LiCl plus [Dmim]I + H2O
    Xuan, Yongmei
    Duan, Bosheng
    Fang, Kaile
    Ding, Yaqi
    Gao, Neng
    Chen, Guangming
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2021, 66 (08): : 3346 - 3353
  • [10] Density, Viscosity, and Excess Properties of MDEA + H2O, DMEA + H2O, and DEEA + H2O Mixtures
    Karunarathne, Sumudu S.
    Eimer, Dag A.
    Oi, Lars E.
    [J]. APPLIED SCIENCES-BASEL, 2020, 10 (09):
12345