Synthesis and X-ray crystal structure of a lead aryl oxide dimer, Pb2(μ-O-2,6-Ph2C6H3)2(O-2,6-Ph2C6H3)2

被引：0

作者：

Van Zandt, W ^{[1
]}

Huffman, JC

Stewart, JL

机构：

[1] Hope Coll, Dept Chem, Holland, MI 49422 USA

[2] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

MAIN GROUP METAL CHEMISTRY | 1998年 / 21卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Pb(II) aryl oxide complex, Pb-2(mu-O-2,6-Ph2C6H3)(2)(O-2,6-Ph2C6H3)(2), was prepared from Pb[N(SiMe3)(2)](2) and two equivalents of 2,6-diphenylphenol. The compound was characterized by X-ray crystallography. The complex forms a trans-bridged dimer with two bridging and two terminal aryl oxide ligands. The geometry about each lead atom is trigonal pyramidal. The four lead-oxygen bridge bonds are nearly identical in length and slightly longer (ca. 0.1 Angstrom) than the two lead-oxygen terminal bonds.

引用

页码：237 / 240

页数：4

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