Quinolone based chemosensor for the naked-eye and spectrophotometric detection of Cu2+ in aqueous media

被引：10

作者：

Patil, Samadhan R. ^{[1
]}

Nandre, Jitendra P. ^{[1
]}

Patil, Prashant A. ^{[1
,2
]}

Bothra, Shilpa ^{[3
]}

Sahoo, Suban K. ^{[3
]}

Klasek, Antonin ^{[4
]}

Rodriguez-Lopez, Julian ^{[5
]}

Mahulikar, Promod P. ^{[1
]}

Patil, Umesh D. ^{[1
]}

机构：

[1] North Maharashtra Univ, Sch Chem Sci, Jalgaon 425001, MS, India

[2] SSVPSs LK Dr PR Ghogrey Sci Coll, Dhule 424001, India

[3] SV Natl Inst Technol, Dept Appl Chem, Surat 395007, Gujarat, India

[4] Tomas Bata Univ, Fac Technol, Dept Chem, CZ-76272 Zlin, Czech Republic

[5] Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim, E-13071 Ciudad Real, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 49卷

关键词：

Chemosensor; Naked-eye detection; Cu2+ ion; Intramolecular charge transfer; INT; COPPER; IONS; RECOGNITION; DISORDERS; EXPOSURE; CELLS;

D O I：

10.1016/j.inoche.2014.09.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 4-hydroxy-2-quinolone based chemosensor (BPHTQ-1) was designed for the spectrophotometric and naked-eye detection of Cu2+. The chemosensor displayed a high selectivity and sensitivity towards Cu2+ in the presence of other competitive metal cations in pure aqueous media. The Cu2+ recognition furnished a distinguishable color change of BPHTQ-1 from colorless to yellow with a significant hyperchromic shift at 300 nm. The S and O atoms of BPHTQ-1 provided a 1:1 binding scaffold for the recognition of Cu2+ ion with a high binding affinity of 19,338 M-1 and a detection limit of 139 mu M, which is quite low compared with World Health Organization (WHO) reports. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：59 / 62

页数：4

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