Flow-facilitated ring opening metathesis polymerization (ROMP) and post-polymerization modification reactions

被引:19
|
作者
Subnaik, Selesha I. [1 ]
Hobbs, Christopher E. [1 ]
机构
[1] Sam Houston State Univ, Dept Chem, Huntsville, TX 77340 USA
基金
美国国家科学基金会;
关键词
THIO-BROMO CLICK; LIVING RADICAL POLYMERIZATION; MEDIATED POLYMERIZATION; ANIONIC-POLYMERIZATION; BOTTLEBRUSH POLYMERS; RAFT POLYMERIZATION; MOLECULAR-WEIGHT; COPOLYMERS; CHEMISTRY; REACTORS;
D O I
10.1039/c9py00822e
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This communication describes the use of flow to facilitate ring opening metathesis polymerization (ROMP) reactions of norbornene-derivatives. Homo-and block copolymers can be prepared with moderate control over molecular weight. These reactions are operationally simple and complete in seconds. Additionally, thio-bromo "click" post-polymerization modifications can be carried out inline.
引用
收藏
页码:4524 / 4528
页数:5
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