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Microwave assisted asymmetric Suzuki-Miyaura and Negishi cross-coupling reactions:: synthesis of chiral binaphthalenes

被引：48
|
作者：
Genov, Miroslav [1 ]
Almorin, Antonio [1 ]
Espinet, Pablo [1 ]
机构：
[1] Univ Valladolid, E-47071 Valladolid, Spain
来源：
TETRAHEDRON-ASYMMETRY | 2007年 / 18卷 / 05期
关键词：
D O I：
10.1016/j.tetasy.2007.03.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Microwave assisted asymmetric Suzuki-Miyaura and Negishi enantioselective cross-coupling reactions are reported for the first time, and have been applied to the rapid synthesis of chiral sterically hindered binaphthalene derivatives in reasonable to excellent yields (65-96%) and fair to good enantioselectivities (43-70% ee). (c) 2007 Elsevier Ltd. All rights reserved.
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页码：625 / 627
页数：3
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