Quantum-to-classical transition in the work distribution for chaotic systems

The work distribution is a fundamental quantity in nonequilibrium thermodynamics mainly due to its connection with fluctuation theorems. Here, we develop a semiclassical approximation to the work distribution for a quench process in chaotic systems that provides a link between the quantum and classical work distributions. The approach is based on the dephasing representation of the quantum Loschmidt echo and on the quantum ergodic conjecture, which states that the Wigner function of a typical eigenstate of a classically chaotic Hamiltonian is equidistributed on the energy shell. Using numerical simulations, we show that our semiclassical approximation accurately describes the quantum distribution as the temperature is increased.