An Unusual Independent 1D Metal-Organic Nanotube with Mesohelical Structure and 1D → 2D Interdigitation

被引：70
|
作者：
Jin, Jun-Cheng [1 ]
Wang, Yao-Yu [1 ]
Liu, Ping [1 ]
Liu, Rui-Ting [1 ]
Ren, Chen [1 ]
Shi, Qi-Zhen [1 ]
机构：
[1] NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem Minist Educ, Shaanxi Key Lab Phys Inorgan Chem, Coll Chem & Mat Sci, Xian 710069, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 05期
基金：
中国国家自然科学基金;
关键词：
HELICAL COORDINATION POLYMER; STRANDED MOLECULAR BRAID; CRYSTAL-STRUCTURE; MIXED-LIGANDS; FRAMEWORK; NETWORKS; CHAINS; ARCHITECTURE; SERIES; WATER;
D O I：
10.1021/cg901201s
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel one-dimensional (1D) metal organic nanotube {[Cd-2(ADC)(2)(bpp)(3)(H2O)](2)center dot 8H(2)O}(n) (MONT-1), based on mixed organic ligands, has been synthesized and characterized. MONT-1 presents the first independent 1D metal organic nanotube with mesohelical structure and a fascinating topology of 1D -> 2D interdigital architecture with side arms. This compound also exhibits high thermal stability and blue-shift emission with large intensity enhancement compared with that of the free ligand and can be explored for potential blue luminescent materials.
引用
收藏
页码：2029 / 2032
页数：4
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