Sulfur edge XANES and XPS spectroscopy of ethanethiol adsorbed on nickel

被引：9

作者：

Syed, JA

Sardar, SA

Yagi, S

Tanaka, K

机构：

[1] Hiroshima Univ, Dept Phys Sci, Hiroshima 7398526, Japan

[2] Nagoya Univ, Dept Crystalline Mat Sci, Nagoya, Aichi 4648603, Japan

来源：

SURFACE SCIENCE | 2004年 / 566卷

关键词：

X-ray absorption spectroscopy; X-ray photoelectron spectroscopy; nickel; sulphur; electrical transport (conductivity; resistivity; mobility; etc.);

D O I：

10.1016/j.susc.2004.06.131

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For the interaction of ethanethiol (C2H5SH) with the Ni(110) surface, we utilize X-ray photoclectron spectroscopy (XPS) and X-ray absorption near-edge spectroscopy (XANES) measurements to identify the adsorbed sulfur species and their orientation on the surface at low temperature. Upon adsorption on the Ni(110) surface, ethanethiolate as well as atomic sulfur is formed. For the ethanethiolate, the S-C bond is found predominantly perpendicular to the substrate as revealed by polarization analysis. A qualitative estimation of charge transfer from substrate to molecule is carried out with the aid of S 1s XPS measurements. (C) 2004 Published by Elsevier B.V.

引用

页码：597 / 602

页数：6

共 50 条

[31] DIRECT DETERMINATION AND QUANTIFICATION OF ORGANIC SULFUR FORMS BY X-RAY PHOTOELECTRON-SPECTROSCOPY (XPS) AND SULFUR K-EDGE ABSORPTION-SPECTROSCOPY
KELEMEN, SR
GEORGE, GN
GORBATY, ML
FUEL PROCESSING TECHNOLOGY, 1990, 24 : 425 - 429
[32] Chemical Speciation of Cadmium and Sulfur K-Edge XANES Spectroscopy in Flooded Paddy Soils Amended with Zerovalent Iron
Hashimoto, Yohey
Yamaguchi, Noriko
SOIL SCIENCE SOCIETY OF AMERICA JOURNAL, 2013, 77 (04) : 1189 - 1198
[33] Sulfur Speciation in Soil by S K-Edge XANES Spectroscopy: Comparison of Spectral Deconvolution and Linear Combination Fitting
Prietzel, Joerg
Botzaki, Anna
Tyufekchieva, Nora
Brettholle, Mareike
Thieme, Juergen
Klysubun, Wantana
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (07) : 2878 - 2886
[34] Chemical state of sulfur in natural and synthetic lazurite by SK-edge xanes and X-ray photoelectron spectroscopy
Fleet, ME
Liu, XY
Harmer, SL
Nesbitt, HW
CANADIAN MINERALOGIST, 2005, 43 : 1589 - 1603
[35] Sulfur K-edge XANES studies of microbial cell walls
Diener, LM
Bleam, WF
Balser, T
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U830 - U830
[36] Magnesium K-edge XANES spectroscopy of geological standards
Yoshimura, Toshihiro
Tamenori, Yusuke
Iwasaki, Nozomu
Hasegawa, Hiroshi
Suzuki, Atsushi
Kawahata, Hodaka
JOURNAL OF SYNCHROTRON RADIATION, 2013, 20 : 734 - 740
[37] SEXAFS STUDIES OF SULFUR ADSORBED ON A NICKEL STEPPED SURFACE
ISHII, H
ASAKURA, K
NAMBA, H
OHTA, T
KITAJIMA, Y
KOSUGI, N
KURODA, H
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 : 365 - 367
[38] Phosphorus K-edge XANES spectroscopy of mineral standards
Ingall, Ellery D.
Brandes, Jay A.
Diaz, Julia M.
de Jonge, Martin D.
Paterson, David
McNulty, Ian
Elliott, W. Crawford
Northrup, Paul
JOURNAL OF SYNCHROTRON RADIATION, 2011, 18 : 189 - 197
[39] AZIMUTHALLY-DEPENDENT X-RAY ABSORPTION NEAR EDGE STRUCTURE FOR SULFUR ADSORBED ON NICKEL(110)
NORMAN, D
RICHARDSON, CH
WARBURTON, DR
THORNTON, G
MCGRATH, R
SETTE, F
JOURNAL DE PHYSIQUE, 1986, 47 (C-8): : 525 - 527
[40] STRUCTURE OF THE SULFUR LAYER ADSORBED ON THE (110) NICKEL FACE
MROZ, S
SURFACE SCIENCE, 1979, 83 (02) : L625 - L629

← 1 2 3 4 5 →