Ba9[NbN4]2O[CN2]-synthesis, crystal structure and Raman spectrum

被引：13
|
作者：
Reckeweg, O [1 ]
DiSalvo, FJ [1 ]
机构：
[1] Cornell Univ, Baker Lab, Dept Chem & Biol Chem, Ithaca, NY 14853 USA
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2003年 / 58卷 / 2-3期
关键词：
cyanamide; nitride; structure elucidation;
D O I：
10.1515/znb-2003-0130
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Red transparent single crystals of Ba-9[NbN4](2)O[CN2] were synthesised by the reaction of BaO coated Ba metal, C and Nb powder in arc-welded Nb ampoules at 1300 K. The title compound was characterised by X-ray single crystal diffraction (P (1) over bar, a = 799.05(2), b = 962.61(2) and c = 1264.38(4) pm; alpha = 75.859(1), beta = 85.745(1) and gamma = 87.8621(8)degrees; Z = 2) and Raman spectroscopy (nu(sym) = 1234 and delta = 632/658/668 cm(-1)). It now seems likely that a nitride-azide compound we previously reported, Bag [NbN4](2)N[N-3], does not exist, but is in fact the title compound.
引用
收藏
页码：201 / 204
页数：4
相关论文
共 50 条
  • [1] Ba9[NBN4]2O[CN2] - Synthesis, crystal structure and Raman spectrum
    Reckeweg, Olaf
    DiSalvo, Francis J.
    [J]. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2003, 58 (2-3): : 201 - 204
  • [2] Single crystal structure and Raman spectrum of Ba3Na2(CN2)4
    Dong, Yongkwan
    DiSalvo, Francis J.
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (05) : 1363 - 1368
  • [3] Crystal structure of nonabarium bis(tetranitridoniobate) nitride azide, Ba9[NbN4]2N[N3]
    Clarke, SJ
    DiSalvo, FJ
    [J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1997, 212 (03): : 309 - 310
  • [4] A metal nitride carbodiimide with a stuffed skutterudite-type structure: Synthesis, crystal structure and IR spectra of (Ba6N 5/6)2[NbN4][CN2]6
    Reckeweg, Olaf
    Somer, Mehmet
    Disalvo, Francis J.
    [J]. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2007, 62 (10): : 1246 - 1250
  • [5] A metal nitride carbodiimide with a stuffed skutterudite-type structure:: Synthesis, crystal structure and IR spectra of (Ba6N5/6)2[NbN4][CN2]6
    Reckeweg, Olaf
    Somer, Mehmet
    DiSalvo, Francis J.
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2007, 62 (10): : 1246 - 1250
  • [6] Preparation and Crystal Structure of Ba4MgF2(CN2)4
    Corral, Anna Olive
    Kubus, Mariusz
    Stroebele, Markus
    Meyer, H. -Juergen
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (05): : 902 - 904
  • [7] Synthesis, Structure, and Electronic Properties of Sn9O5Cl4(CN2)2
    Loeber, Manuel
    Geissenhoener, Chris Steve
    Stroebele, Markus
    Indris, Sylvio
    Romao, Carl P.
    Meyer, Hans-Juergen
    [J]. INORGANIC CHEMISTRY, 2019, 58 (21) : 14560 - 14567
  • [8] Synthesis, Raman Spectrum and Single-Crystal Structure of CaBa8[CN2]6O2(N0.5H0.5)
    Reckeweg, Olaf
    Schulz, Armin
    DiSalvo, Francis J.
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (01): : 39 - 43
  • [9] Synthesis, Structure and Electronic Properties of Sn(CN2) and Sn4Cl2(CN2)3
    Loeber, Manuel
    Dolabdjian, Konstantin
    Stroebele, Markus
    Romao, Carl P.
    Meyer, Hans-Juergen
    [J]. INORGANIC CHEMISTRY, 2019, 58 (12) : 7845 - 7851
  • [10] Synthesis and Crystal Structure of LiY(CN2)2, Having a Structure Related to That of NiAs
    Unverfehrt, Leonid
    Stroebele, Markus
    Meyer, H-Juergen
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (01): : 22 - 24
12345