3D Printing Phosphonium Ionic Liquid Networks with Mask Projection Microstereolithography

被引：85
|
作者：
Schultz, Alison R. [2 ]
Lambert, Philip M. [1 ]
Chartrain, Nicholas A. [1 ]
Ruohoniemi, David M. [2 ]
Zhang, Zhiyang [2 ]
Jangu, Chainika [2 ]
Zhang, Musan [2 ]
Williams, Christopher B. [1 ]
Long, Timothy E. [2 ]
机构：
[1] Virginia Tech, Dept Mech Engn, Blacksburg, VA 24061 USA
[2] Virginia Tech, Dept Chem, Macromol & Interfaces Inst, Blacksburg, VA 24061 USA
来源：
ACS MACRO LETTERS | 2014年 / 3卷 / 11期
基金：
美国国家科学基金会;
关键词：
CONTAINING ELECTROACTIVE MEMBRANES; ABA TRIBLOCK COPOLYMERS; EXCHANGE MEMBRANES; LITHIUM ION; POLYMERIZATION; CONDUCTION; POLYMERS; TRANSPORT; AMMONIUM; COATINGS;
D O I：
10.1021/mz5006316
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Photopolymerization coupled with mask projection micro-.stereolithography successfully generated various 3D printed phosphonium polymerized ionic liquids (PILs) with low UV light intensity requirements and high digital resolution. Varying phosphonium monomer concentration, diacrylate cross-linking comonomer, and display images enabled precise 3D design and polymeric properties. The resulting cross-linked phosphonium PIL objects exhibited a synergy of high thermal stability, tunable glass transition temperature, optical clarity, and ion conductivity, which are collectively well-suited for emerging electro-active membrane technologies. Ion conductivity measurements on printed objects revealed a systematic progression in conductivity with ionic liquid monomer content, and thermal properties and solvent extraction demonstrated the formation of a polymerized ionic liquid network, with gel fractions exceeding 95%.
引用
收藏
页码：1205 / 1209
页数：5
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