Unsupported Nanoporous Gold-Catalyzed Chemoselective Reduction of α,β-Unsaturated Aldehydes Using Formic Acid as Hydrogen Source

被引：13

作者：

Butt, Madiha ^{[1
]}

Feng, Xiujuan ^{[1
]}

Yamamoto, Yoshinori ^{[1
,2
]}

Almansour, Abdulrahman I. ^{[3
]}

Arumugam, Natarajan ^{[3
]}

Kumar, Raju Suresh ^{[3
]}

Bao, Ming ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China

[2] Tohoku Univ, WPI AIMR, Sendai, Miyagi 9808577, Japan

[3] King Saud Univ, Dept Chem, Coll Sci, POB 2455, Riyadh 11451, Saudi Arabia

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 6卷 / 07期

基金：

中国国家自然科学基金;

关键词：

allylic compounds; chemoselectivity; aldehydes; formic acid; reduction; HIGHLY SELECTIVE HYDROGENATION; LIQUID-PHASE HYDROGENATION; AEROBIC OXIDATION; ALLYLIC ALCOHOLS; NANOSTRUCTURED MATERIALS; SKELETON CATALYSTS; CARBONYL-COMPOUNDS; AU/CEO2; CATALYSTS; LOW-TEMPERATURE; FINE CHEMICALS;

D O I：

10.1002/ajoc.201700130

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A straightforward, highly chemoselective hydrogenation of ,-unsaturated aldehydes was developed using unsupported nanoporous gold (AuNPore) as a heterogeneous catalyst with bio-renewable formic acid (HCO2H) as hydrogen source. Various alpha,beta-unsaturated aldehydes were reduced to their corresponding allylic alcohols in good to high chemical yields with excellent selectivity. AuNPore offers several attractive features as a catalyst, such as high activity and selectivity, easy recyclability, and no leaching.

引用

页码：867 / 872

页数：6

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