Unsupported Nanoporous Gold-Catalyzed Chemoselective Reduction of α,β-Unsaturated Aldehydes Using Formic Acid as Hydrogen Source

被引：13
|
作者：
Butt, Madiha [1 ]
Feng, Xiujuan [1 ]
Yamamoto, Yoshinori [1 ,2 ]
Almansour, Abdulrahman I. [3 ]
Arumugam, Natarajan [3 ]
Kumar, Raju Suresh [3 ]
Bao, Ming [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China
[2] Tohoku Univ, WPI AIMR, Sendai, Miyagi 9808577, Japan
[3] King Saud Univ, Dept Chem, Coll Sci, POB 2455, Riyadh 11451, Saudi Arabia
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 6卷 / 07期
基金：
中国国家自然科学基金;
关键词：
allylic compounds; chemoselectivity; aldehydes; formic acid; reduction; HIGHLY SELECTIVE HYDROGENATION; LIQUID-PHASE HYDROGENATION; AEROBIC OXIDATION; ALLYLIC ALCOHOLS; NANOSTRUCTURED MATERIALS; SKELETON CATALYSTS; CARBONYL-COMPOUNDS; AU/CEO2; CATALYSTS; LOW-TEMPERATURE; FINE CHEMICALS;
D O I：
10.1002/ajoc.201700130
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A straightforward, highly chemoselective hydrogenation of ,-unsaturated aldehydes was developed using unsupported nanoporous gold (AuNPore) as a heterogeneous catalyst with bio-renewable formic acid (HCO2H) as hydrogen source. Various alpha,beta-unsaturated aldehydes were reduced to their corresponding allylic alcohols in good to high chemical yields with excellent selectivity. AuNPore offers several attractive features as a catalyst, such as high activity and selectivity, easy recyclability, and no leaching.
引用
收藏
页码：867 / 872
页数：6
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