Fixation of atmospheric nitrogen: Synthesis of heterocycles with atmospheric nitrogen as the nitrogen source

被引：0

作者：

Mori, M ^{[1
]}

Hori, K ^{[1
]}

Akashi, M ^{[1
]}

Hori, M ^{[1
]}

Sato, Y ^{[1
]}

Nishida, M ^{[1
]}

机构：

[1] Hokkaido Univ, Fac Pharmaceut Sci, Sapporo, Hokkaido 060, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 05期

关键词：

heterocycles; lycopodine; nitrogen fixation; titanium;

D O I：

10.1002/(SICI)1521-3773(19980316)37:5<636::AID-ANIE636>3.0.CO;2-X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dry air is the source of molecular nitrogen for reactions with TiL4, Li, and TMSC1 (L = Cl, OiPr; TMS = trimethylsilyl). The nitrogen-titanium complexes thus prepared can be used to synthesize indoles, pyrroles, and lactams from carbonyl compounds. Applying this method to 1 provides access to 2, the key compound in the synthesis of (±)-lycopodine.

引用

页码：636 / 637

页数：2

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