Preparation of 2-iodo-1,3-butadienes from 1-trimethylsilyl-2,3-butadienes and their functionalizations

被引：29

作者：

Nishiyama, T ^{[1
]}

Esumi, T ^{[1
]}

Iwabuchi, Y ^{[1
]}

Irie, H ^{[1
]}

Hatakeyama, S ^{[1
]}

机构：

[1] Nagasaki Univ, Fac Pharmaceut Sci, Nagasaki 852, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 1-2期

关键词：

D O I：

10.1016/S0040-4039(97)10413-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Successive treatment of 1-trimethylsilyl-2,3-butadienes with iodine and tetra-n-butylammonium fluoride in the same flask affords 2-iodo-1,3-butadienes in good yields and their palladium-catalyzed carbonylation and alkynylation allows introduction of ester and alkynyl groups to the 2-position bearing an iodine atom leading to various 2,3-disubstituted 1,3-butadienes. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：43 / 46

页数：4

共 50 条

[1] Preparation of 2-Iodo-1,3-butadienes from 1-Trimethylsilyl-2,3-butadienes and their Functionalizations
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