Self-assembly of modified silica nanospheres at the liquid/liquid interface

被引：8
|
作者：
He, J. X. [1 ,2 ]
Cui, M. Y. [1 ,2 ]
Zheng, Y. Y. [1 ,2 ]
Tang, W. H. [1 ,2 ]
Chen, B. Y. [1 ,2 ]
Tsukamoto, K. [3 ,4 ]
Li, C. R. [1 ,2 ,3 ,4 ]
机构：
[1] Zhejiang Sci Tech Univ, Minist Educ, Dept Phys, Ctr Optoelect Mat & Devices, Hangzhou 310018, Zhejiang, Peoples R China
[2] Zhejiang Sci Tech Univ, Minist Educ, Key Lab ATMMT, Hangzhou 310018, Zhejiang, Peoples R China
[3] Tohoku Univ, Interdisciplinary Res Ctr, Sendai, Miyagi 9808578, Japan
[4] Tohoku Univ, Grad Sch Sci, Sendai, Miyagi 9808578, Japan
来源：
MATERIALS LETTERS | 2010年 / 64卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Thin films; Crystal structure; Self-assemble; Liquid/liquid interface; PHOTONIC CRYSTALS; NANOPARTICLES; GROWTH; SPHERES;
D O I：
10.1016/j.matlet.2009.11.048
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A stabilized 2 or 3D silica sphere structure was Successfully prepared by a 3-step method. First, the surfaces of silica spheres were modified with a functional silane coupling agent 3-methacryloxypropyltrimethoxysilane (gamma-MPS); then, the surface-modified silica spheres were self-assembled at the liquid/liquid interface to fabricate a two- or three-dimensional ordered structure; and finally, the formed ordered structure was stabilized by a stable polymerization reaction among the modified silica spheres. The polymerized silica sphere film can be transferred from solution to quartz Substrates without destroying its ordered structure. This ordered structure could be potentially used as a photonic band gap material or the template for fabrication of other highly ordered structures. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：463 / 465
页数：3
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