Diagnostic Criteria for the Characterization of Electrode Reactions with Chemical Reactions Following Electron Transfer by Cyclic Square Wave Voltammetry

被引：7
|
作者：
Helfrick, John C., Jr. [1 ]
Mann, Megan A. [1 ]
Bottomley, Lawrence A. [1 ]
机构：
[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
来源：
ELECTROCHIMICA ACTA | 2016年 / 205卷
关键词：
Square wave voltammetry; theory; chemically-coupled electrode reaction; cyclic square wave voltammetry; EC mechanism; LINEAR SWEEP VOLTAMMETRY; STAIRCASE VOLTAMMETRY; SPHERICAL ELECTRODES; GENERAL EQUIVALENCE; EC; SCAN; POLAROGRAPHY; SIMULATION;
D O I：
10.1016/j.electacta.2016.04.006
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Theory for cyclic square wave voltammetry of electrode reactions with coupled chemical reactions following the electron transfer is presented. Theoretical voltammograms were calculated following systematic variation of empirical parameters to assess their impact on the shape of the voltammogram. From the trends obtained, diagnostic criteria for this mechanism were deduced. When properly applied, these criteria will enable non-experts in voltammetry to assign the electrode reaction mechanism and accurately measure reaction kinetics. (C) 2016 Published by Elsevier Ltd.
引用
收藏
页码：20 / 28
页数：9
相关论文
共 50 条
  • [1] Diagnostic Criteria for the Characterization of Electrode Reactions with Chemically Coupled Reactions Preceding the Electron Transfer by Cyclic Square Wave Voltammetry
    Helfrick, John C., Jr.
    Mann, Megan A.
    Bottomley, Lawrence A.
    [J]. CHEMPHYSCHEM, 2016, 17 (16) : 2596 - 2606
  • [2] Diagnostic Criteria for the Characterization of Quasireversible Electron Transfer Reactions by Cyclic Square Wave Voltammetry
    Mann, Megan A.
    Helfrick, John C., Jr.
    Bottomley, Lawrence A.
    [J]. ANALYTICAL CHEMISTRY, 2014, 86 (16) : 8183 - 8191
  • [3] Cyclic Square Wave Voltammetry of Single and Consecutive Reversible Electron Transfer Reactions
    Helfrick, John C., Jr.
    Bottomley, Lawrence A.
    [J]. ANALYTICAL CHEMISTRY, 2009, 81 (21) : 9041 - 9047
  • [4] Cyclic square wave voltammetry of electrode reactions with nonunity stoichiometry
    Laborda, Eduardo
    Maria Gomez-Gil, Jose
    Lopez-Tenes, Manuela
    Molina, Angela
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2020, 873
  • [5] Cyclic Square Wave Voltammetry of Surface-Confined Quasireversible Electron Transfer Reactions
    Mann, Megan A.
    Bottomley, Lawrence A.
    [J]. LANGMUIR, 2015, 31 (34) : 9511 - 9520
  • [6] CYCLIC SQUARE-WAVE VOLTAMMETRY OF KINETICALLY CONTROLLED SINGLE AND MULTIPLE STEP ELECTRON-TRANSFER REACTIONS
    BOTTOMLEY, LA
    HELFRICK, JC
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 116 - ANYL
  • [7] Theory of Square-wave Voltammetry of two Electrode Reactions Coupled by Reversible Chemical Reaction
    Komorsky-Lovric, Sebojka
    Lovric, Milivoj
    [J]. ANALYTICAL & BIOANALYTICAL ELECTROCHEMISTRY, 2013, 5 (03): : 291 - 304
  • [8] Characterizing electrode reactions by multisampling the current in square-wave voltammetry
    Mirceski, Valentin
    Guziejewski, Dariusz
    Bozem, Monika
    Bogeski, Ivan
    [J]. ELECTROCHIMICA ACTA, 2016, 213 : 520 - 528
  • [9] ISOPOTENTIAL POINTS IN SQUARE-WAVE VOLTAMMETRY OF REVERSIBLE ELECTRODE REACTIONS
    Zelic, Marina
    Lovric, Milivoj
    [J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2009, 74 (10) : 1489 - 1501
  • [10] Square-wave voltammetry of quasi-reversible electrode processes with coupled homogeneous chemical reactions
    Garay, F
    Lovric, M
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2002, 518 (02): : 91 - 102
12345