In-situ TEM and EELS studies of alkali-metal intercalation with single-walled carbon nanotubes

被引：75
|
作者：
Suzuki, S [1 ]
Bower, C
Zhou, O
机构：
[1] NTT, Sci & Core Technol Lab Grp, Musashino, Tokyo 180, Japan
[2] Univ N Carolina, Dept Phys & Astron, Chapel Hill, NC 27599 USA
[3] Univ N Carolina, Curruculum Appl & Mat Sci, Chapel Hill, NC 27599 USA
来源：
CHEMICAL PHYSICS LETTERS | 1998年 / 285卷 / 3-4期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0009-2614(98)00051-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cesium (Cs) or potassium (K) was deposited on single-walled carbon nanotube bundles in vacuum at room temperature. The deposited bundles were analyzed in-situ by transmission electron microscopy and electron energy loss spectroscopy techniques, The results indicate that both Cs and K can be reversibly intercalated with the bundles. The intercalants reside in-between the individual nanotubes within the bundles. Intercalation caused structural disorder to the two-dimensional lattice of the pristine nanotube bundles. The chemical compositions of the nanotube bundles intercalated with K and Cs were found to be about KC24 and CsC24 to CsC8. (C) 1998 Elsevier Science B.V.
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收藏
页码：230 / 234
页数：5
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