Catalytic oxidation of nicotine over zeolite-supported platinum

被引:10
|
作者
Gerard-Gomez, C
Dufaux, M
Morel, J
Naccache, C
Ben Taarit, Y
机构
[1] Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France
[2] Univ Havre, Chim Lab, F-76600 Le Havre, France
关键词
nicotine; platinum/zeolite;
D O I
10.1016/S0926-860X(97)00219-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Platinum loaded NaY, HY and dealuminated HY were shown to be active in the total oxidation of nicotine at 573 K into CO2, H2O and N-2 at the exclusion of CO and NOx. The activity (turnover frequency (TOF)) of a surface metal atom was independent of the method of metal loading (ion-exchange or impregnation) but increased with the metal particle size. Compared to non-porous silica, zeolites exerted a beneficial effect on metal particles of similar sizes, presumably, because a shielding effect of the acidic zeolite matrix with respect to the nicotine base. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:371 / 377
页数:7
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